Synthesis of water-soluble phosphines having polyether substituents and their application to transition metal-catalyzed water gas shift reaction.
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Uncatalyzed and Wall-catalyzed Forward Water-gas Shift Reaction Kinetics
The kinetics of the high-temperature (1070-1134 K), low and high-pressure gasphase forward water-gas shift reaction were evaluated in an empty quartz reactor and a quartz reactor packed with quartz particles. The power law expression for the reaction rate was consistent with the Bradford mechanism and was invariant with respect to pressure. The experimental rate constant was lower than that pub...
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ژورنال
عنوان ژورنال: NIPPON KAGAKU KAISHI
سال: 1985
ISSN: 2185-0925,0369-4577
DOI: 10.1246/nikkashi.1985.486